The font family is located within the "Font" option in the text Properties. Dreamweaver lists both a "Default Font" option and a list of font series. Choose the font series that best suits your needs or click on "Edit Font List..." to create a new series.
Change the Font Family
Modify Text with Dreamweaver
Change the Font Family
Screen shot by J KyrninMore Help with Font Families
What are generic font families?Understand Web TypographySpecifying a Series of Font Families
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